Dispatch received the call around 1 p.m. Both children were taken to the E.R.
Officers with the Hazard Police Department responded to the incident. They said it was not a hit-and-run, and officers are continuing to investigate.
Officers with Hazard Police Department said the woman responsible for hitting the two children is Holly Combs. Police said Combs was high on drugs at the time of the crash. They say they also found meth, Suboxone and Xanax in Combs' vehicle.
Officers arrested Combs and charged her with DUI - controlled substances, assault, wanton endangerment and drug possession.